Proceedings of the Chemical Society Volume 21

Proceedings of the Chemical Society Volume 21

Proceedings of the Chemical Society Volume 21 by Chemical Society
Proceedings of the Chemical Society Volume 21
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Author: Chemical Society
Number of Pages: 138 pages
Published Date: 19 May 2012
Publisher: Not Avail
Publication Country: Miami Fl, United States
Language: English
ISBN: 9781236207470
File Name: Proceedings.of.the.Chemical.Society.Volume.21.pdf
Download Link: Proceedings of the Chemical Society Volume 21
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This historic book may have numerous typos and missing text. Purchasers can download a free scanned copy of the original book (without typos) from the publisher. Not indexed. Not illustrated. 1906 Excerpt: ..."Complex nitrites of bismuth." By W. C. Ball. "C-Phenyl-s-triazole." By G. Young. R. CLAY AND SONS, LTD., BRKAD ST. HILL, K.C., AND BUNOAY, SOFFOLK. Wednesday, April 19th, 1905. Professor R. Meldola, F.R.S., President, in the Chair. Mr. B. Perrott was formally admitted a Fellow of the Society. Certificates were read for the first time in favour of Messrs.: Joseph Bennett, North Adams, Mass., U.S.A. Ralph Emerson De Lury, M.A., Manilla, Ontario, Canada. Robert Donald, M.A., B.Sc., M.R.C.S., L.R.C.P., D.P.H., 75, Clyde Street, Dunedin, N.Z. Ernest Lyle Carman Forster, M.A., Brampton, Ontario, Canada. Of the following papers, those marked were read: 69. "Complex nitrites of bismuth." By Walter Craven Ball. A very unstable, yellow, crystalline substance, probably Bi(N02)s,2NH4-NO, NH4-NOs, NaN08, is precipitated by dissolving bismuth nitrate in sodium nitrite solution and pouring the resulting orange-coloured liquid into a saturated solution of ammonium nitrate at 0. A more stable yellow compound, bismuth sodium ammonium nitrite, Bi(N02)8,2NH4, N02, NaN02, which crystallises in octahedra, is obtained by dissolving bismuth nitrate in concentrated ammonium nitrate solution and adding the resulting liquid to a saturated solution of sodium nitrite, cooled to 0, and acidified with nitrous fumes. A fairly stable, orange-yellow, bismuth potassium nitrite, Bi(NO2)3,3KN02, H2O, is formed when nitrous fumes are passed into bismuth hydroxide suspended in a concentrated solution of potassium nitrite. All these salts, which are decomposed by water, have a slight green fluorescence. Discussion. Dr. L. F. Guttmann said that if the compounds described were analogous to the complex cobaltinitrites, it should be possible to prepare the corresponding bar...

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